Highly-controlled regiospecific free-radical copolymerization of 1,3-diene monomers with sulfur dioxide

Naruki Tanaka; Eriko Sato; Akikazu Matsumoto

doi:10.1039/C1OB05169E

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Organic & Biomolecular Chemistry

Issue 10, 2011

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Highly-controlled regiospecific free-radical copolymerization of 1,3-diene monomers with sulfur dioxide

Naruki Tanaka , Eriko Sato and Akikazu Matsumoto

Org. Biomol. Chem., 2011,9, 3753-3758

DOI: 10.1039/C1OB05169E
Received 31 Jan 2011, Accepted 23 Mar 2011
First published on the web 23 Mar 2011
This article is part of the collection: Free Radical Chemistry special themed issue in memory of Athel Beckwith

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Abstract
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The free-radical copolymerization of alkyl-substituted 1,3-butadienes with sulfur dioxide using a redox initiating system in toluene at −78 °C produced poly(diene sulfone)s consisting of a highly alternating and 1,4-regiospecific repeating structure, irrespective of the position and number of alkyl substituents, and the highly regioselective propagation via a free radical reaction mechanism is well accounted for by DFT calculations using model reactions.

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Highly-controlled regiospecific free-radical copolymerization of 1,3-diene monomers with sulfur dioxide

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