Structure–activity studies of the pelorusides: new congeners and semi-synthetic analogues

A. Jonathan Singh; Mina Razzak; Paul Teesdale-Spittle; Thomas N. Gaitanos; Anja Wilmes; Ian Paterson; Jonathan M. Goodman; John H. Miller; Peter T. Northcote

doi:10.1039/C0OB01127D

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Organic & Biomolecular Chemistry

Issue 12, 2011

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Structure–activity studies of the pelorusides: new congeners and semi-synthetic analogues

A. Jonathan Singh , Mina Razzak , Paul Teesdale-Spittle , Thomas N. Gaitanos , Anja Wilmes , Ian Paterson , Jonathan M. Goodman , John H. Miller and Peter T. Northcote

Org. Biomol. Chem., 2011,9, 4456-4466

DOI: 10.1039/C0OB01127D
Received 06 Dec 2010, Accepted 21 Mar 2011
First published on the web 23 Mar 2011

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Abstract
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Two new peloruside congeners (3 and 4) were isolated from wild and aquacultured collections of the New Zealand marine sponge Mycale hentscheli. Small-scale reactions on peloruside A (1) have been performed, which along with the isolation of 3 and 4, give further insight into the bioactive pharmacophore of 1.