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Departamento de Ingeniería Química Industrial, Escuela Técnica Superior de Ingenieros Industriales, Universidad Politécnica de Madrid, Madrid 28006, Spain
; Fax: +34 913363184
; Tel: +34 913363184
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, C/Francisco Tomás y Valiente 7, Cantoblanco, Madrid, Spain
; Fax: +34 914974833
; Tel: +34 914978757
New J. Chem., 2011,35, 2187-2195
01 Mar 2011,
01 Jun 2011
First published online
27 Jun 2011
The reaction of bis(ferrocenyl)methylsilane1 with two carbosilane dendritic cores containing terminal allyl units gives dendrimers functionalized with eight interacting ferrocenyl units. They show two reversible ferrocenyl waves in cyclic voltammetry (CV) and form derivatized Ptelectrodes. Platinumelectrodes modified with electrodeposited films of these two dendrimers exhibit electrocatalytic activity towards the reduction of oxygen and both oxidation and reduction of hydrogen peroxide. The molecular structure of 1 has been determined by single-crystal X-ray diffraction studies.
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