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Issue 7, 2011
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α,β-D-CNA featuring canonical and noncanonical α/β torsional angles behaviours within oligonucleotides

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Abstract

α,β-D-CNA building blocks featuring either canonical gauche(−) or noncanonical gauche(+) values of the nucleic acids sugar phosphate backbone torsional angle α have been introduced into oligonucleotides, and provide new insight on conformational restriction impact on duplex formation ability by means of UV experiments and molecular dynamics simulations.

Graphical abstract: α,β-D-CNA featuring canonical and noncanonical α/β torsional angles behaviours within oligonucleotides

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Publication details

The article was received on 31 Jan 2011, accepted on 20 Apr 2011 and first published on 17 May 2011


Article type: Paper
DOI: 10.1039/C1NJ20086K
Citation: New J. Chem., 2011,35, 1528-1533
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    α,β-D-CNA featuring canonical and noncanonical α/β torsional angles behaviours within oligonucleotides

    A. Boissonnet, C. Dupouy, P. Millard, M. Durrieu, N. Tarrat and J. Escudier, New J. Chem., 2011, 35, 1528
    DOI: 10.1039/C1NJ20086K

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