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Issue 2, 2011
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Hybridization of clay minerals with the floating film of a cationic Ir(III) complex at an air–water interface

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Abstract

The Langmuir–Blodgett films were prepared by hybridizing the clay minerals (synthetic saponite, synthetic hectorite and sodium montmorillonite) with the floating film of a cationic Ir(III) complex, [Ir(ppy)2(dc18bpy)]+ (ppy = 2-phenylpyridine; dc18bpy = 4,4′-dioctadecyl-2,2′-bipyridine). When the single-layered hybrid LB film was irradiated at 430 nm, it emitted light in the visible region, whose intensity responded reversibly to the pressure change of oxygen.

Graphical abstract: Hybridization of clay minerals with the floating film of a cationic Ir(iii) complex at an air–water interface

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Publication details

The article was received on 08 Jul 2010, accepted on 01 Oct 2010 and first published on 28 Oct 2010


Article type: Paper
DOI: 10.1039/C0NJ00534G
Citation: New J. Chem., 2011,35, 394-399
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    Hybridization of clay minerals with the floating film of a cationic Ir(III) complex at an air–water interface

    H. Sato, K. Tamura, K. Ohara, S. Nagaoka and A. Yamagishi, New J. Chem., 2011, 35, 394
    DOI: 10.1039/C0NJ00534G

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