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Issue 17, 2011
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A new approach to synthesis of periodic mesoporous organosilicas: taking advantage of self-assembly and reactivity of organic precursors

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Abstract

A new approach to the synthesis of multifunctional organosilicas that combines the self-assembly formation of an ordered mesostructure with chemical reactions for the creation of new organic groups is proposed. This strategy was employed to prepare ordered ethane–silica mesostructures with N-hydroxyurea and N,N′-ureidopropyl-(phenylboronic acid) groups formed because of using two reactive precursors in addition to a primary organosilane, bis(triethoxysilyl)ethane, the major component of the framework.

Graphical abstract: A new approach to synthesis of periodic mesoporous organosilicas: taking advantage of self-assembly and reactivity of organic precursors

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Publication details

The article was received on 21 Jan 2011, accepted on 22 Feb 2011 and first published on 23 Mar 2011


Article type: Paper
DOI: 10.1039/C1JM10322A
Citation: J. Mater. Chem., 2011,21, 6389-6394
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    A new approach to synthesis of periodic mesoporous organosilicas: taking advantage of self-assembly and reactivity of organic precursors

    S. Gu and M. Jaroniec, J. Mater. Chem., 2011, 21, 6389
    DOI: 10.1039/C1JM10322A

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