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Issue 45, 2011
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Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(III) luminescent “half-helicates”

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Abstract

The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH3CN give rise to the formation of lanthanide luminescent ‘half-helicates’ in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.

Graphical abstract: Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates”

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Publication details

The article was received on 27 Jun 2011, accepted on 18 Aug 2011 and first published on 22 Sep 2011


Article type: Communication
DOI: 10.1039/C1DT11225B
Citation: Dalton Trans., 2011,40, 12056-12059
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    Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(III) luminescent “half-helicates”

    C. Lincheneau, C. Destribats, D. E. Barry, J. A. Kitchen, R. D. Peacock and T. Gunnlaugsson, Dalton Trans., 2011, 40, 12056
    DOI: 10.1039/C1DT11225B

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