Issue 45, 2011
From the journal:

Dalton Transactions

Encapsulation of trivalent phosphate anion within a rigidified π-stacked dimeric capsular assembly of tripodal receptor†

Sandeep Kumar Deya  and  Gopal Das*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Guwahati, Assam, India
E-mail: gdas@iitg.ernet.in
Fax: +91-361-258-2349
Tel: +91-361-258-2313

Abstract

The tris(thiourea) receptor, L, in the presence of excess H2PO4− has been found to encapsulate a trivalent phosphate ion within a π-stacked dimeric capsular assembly of the receptor with twelve strong H-bonds via deprotonation, as evident from the origin of a new set of signals in the 1H NMR titration experiments.

Graphical abstract: Encapsulation of trivalent phosphate anion within a rigidified π-stacked dimeric capsular assembly of tripodal receptor

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Article information

DOI
https://doi.org/10.1039/C1DT11195G
Article type
Communication
Submitted
23 Jun 2011
Accepted
17 Aug 2011
First published
16 Sep 2011

Dalton Trans., 2011,40, 12048-12051

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Encapsulation of trivalent phosphate anion within a rigidified π-stacked dimeric capsular assembly of tripodal receptor

S. K. Dey and G. Das, Dalton Trans., 2011, 40, 12048 DOI: 10.1039/C1DT11195G

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