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Issue 41, 2011
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Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide

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Abstract

The structure of TcCo2O4 has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc–O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent.

Graphical abstract: Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide

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Publication details

The article was received on 21 May 2011, accepted on 28 Jul 2011 and first published on 06 Sep 2011


Article type: Paper
DOI: 10.1039/C1DT10954E
Citation: Dalton Trans., 2011,40, 10924-10926
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    Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide

    G. J. Thorogood, Z. Zhang, J. R. Hester, B. J. Kennedy, J. Ting, C. J. Glover and B. Johannessen, Dalton Trans., 2011, 40, 10924
    DOI: 10.1039/C1DT10954E

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