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Issue 33, 2011
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Non-classical hydrogen bonding in [K(1-aza-18-crown-6)]BH4 and its 18-crown-6 counterpart

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Abstract

The extended structures of [K(1-aza-18-crown-6)]BH4 and its 18-crown-6 analogue exhibits significantly different primary and secondary stabilizing interactions. However, their respective ion pairs display similar cation-to-anion interactions, in spite of the differences in the nature of the crown ether ligand.

Graphical abstract: Non-classical hydrogen bonding in [K(1-aza-18-crown-6)]BH4 and its 18-crown-6 counterpart

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Publication details

The article was received on 11 May 2011, accepted on 13 Jun 2011 and first published on 29 Jun 2011


Article type: Communication
DOI: 10.1039/C1DT10888C
Citation: Dalton Trans., 2011,40, 8301-8303
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    Non-classical hydrogen bonding in [K(1-aza-18-crown-6)]BH4 and its 18-crown-6 counterpart

    D. J. Wolstenholme, P. Sirsch, L. Onut, J. Flogeras, A. Decken and G. S. McGrady, Dalton Trans., 2011, 40, 8301
    DOI: 10.1039/C1DT10888C

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