The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

Chris Ritchie; Chloë E. Miller; Colette Boskovic

doi:10.1039/C1DT10866B

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres†

Chris Ritchie,^a Chloë E. Miller^a and Colette Boskovic*^a

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* Corresponding authors

^a School of Chemistry, University of Melbourne, Melbourne, Victoria, Australia
E-mail: c.boskovic@unimelb.edu.au

Abstract

A new polyoxometalate-based 3D framework K₅Na[K₂{Dy(H₂O)₃}₂{As₂W₁₉O₆₈}{WO₂(pic)}₂] (1) (pic = 2-picolinate), composed of picolinate-functionalised dysprosium-containing tungstoarsenates and distorted potassium–picolinate cubane units, has been synthesised from the polyoxometalate precursor [As₂W₁₉O₆₇(H₂O)]¹⁴⁻.

This article is part of the themed collection: Self-assembly in inorganic chemistry

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Crystal structure data TXT (187K)

Article information

DOI: https://doi.org/10.1039/C1DT10866B
Article type: Communication
Submitted: 09 May 2011
Accepted: 20 Jul 2011
First published: 15 Aug 2011

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Dalton Trans., 2011,40, 12037-12039

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

C. Ritchie, C. E. Miller and C. Boskovic, Dalton Trans., 2011, 40, 12037 DOI: 10.1039/C1DT10866B

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres†

Abstract

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

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