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Issue 22, 2011
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New hexaphosphane ligands 1,3,5-C6H3{p-C6H4N(PX2)2}3 [X = Cl, F, C6H3OMe(C3H5)]: Synthesis, derivatization and palladium(II) and platinum(II) complexes

Sowmya Rao,a  Chelladurai Ganesamoorthy,a  Shaikh M. Mobinb  and  Maravanji S. Balakrishna*a 
Author affiliations

* Corresponding authors

a Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, India
E-mail: krishna@chem.iitb.ac.in
Fax: +91 22 2576 7152/2572 3480
Tel: +91 22 2576 7181

b National Single Crystal X-ray Diffraction Facility, Indian Institute of Technology Bombay, Powai, Mumbai, India

Abstract

A novel dodecachlorohexaphosphane, 1,3,5-C6H3[p-C6H4N(PCl2)2]3 (1) was synthesized by reacting 1,3,5-tris(4′-anilino)benzene with phosphorus trichloride. Fluorination of 1 with SbF3 produces 1,3,5-C6H3[p-C6H4N(PF2)2]3 (2). The derivatization of chlorohexaphosphane with an aryloxy substituent and its palladium(II) and platinum(II) complexes are also described.

Graphical abstract: New hexaphosphane ligands 1,3,5-C6H3{p-C6H4N(PX2)2}3 [X = Cl, F, C6H3OMe(C3H5)]: Synthesis, derivatization and palladium(ii) and platinum(ii) complexes

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Publication details

The article was received on 18 Mar 2011, accepted on 11 Apr 2011 and first published on 09 May 2011


Article type: Communication
DOI: 10.1039/C1DT10459D
Citation: Dalton Trans., 2011,40, 5841-5843
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    New hexaphosphane ligands 1,3,5-C6H3{p-C6H4N(PX2)2}3 [X = Cl, F, C6H3OMe(C3H5)]: Synthesis, derivatization and palladium(II) and platinum(II) complexes

    S. Rao, C. Ganesamoorthy, S. M. Mobin and M. S. Balakrishna, Dalton Trans., 2011, 40, 5841
    DOI: 10.1039/C1DT10459D

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