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Issue 19, 2011
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Broadening the reactivity spectrum of a phthalocyanine catalyst while suppressing its nucleophilic, electrophilic and radical degradation pathways

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Abstract

A robust molecule that resists degradationvia nucleophilic, electrophilic and radical attacks is described. Coordinated O2 is reduced catalytically, producing efficiently thyil radicals in spite of the extreme electronic deficiency of the catalyst.

Graphical abstract: Broadening the reactivity spectrum of a phthalocyanine catalyst while suppressing its nucleophilic, electrophilic and radical degradation pathways

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Publication details

The article was received on 17 Mar 2011, accepted on 23 Mar 2011 and first published on 05 Apr 2011


Article type: Communication
DOI: 10.1039/C1DT10458F
Citation: Dalton Trans., 2011,40, 5162-5165
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    Broadening the reactivity spectrum of a phthalocyanine catalyst while suppressing its nucleophilic, electrophilic and radical degradation pathways

    A. Loas, R. Gerdes, Y. Zhang and S. M. Gorun, Dalton Trans., 2011, 40, 5162
    DOI: 10.1039/C1DT10458F

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