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Issue 30, 2011
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Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

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Abstract

Dehydrogenation of Me2NH·BH3 (1) by group 4 metallocene alkyne complexes of the type Cp2M(L)(η2-Me3SiC2SiMe3) [Cp = η5-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe2)4 [M = Ti (8Ti), Zr (8Zr)] is presented.

Graphical abstract: Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

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Publication details

The article was received on 23 Mar 2011, accepted on 04 Apr 2011 and first published on 21 Apr 2011


Article type: Communication
DOI: 10.1039/C1DT10366K
Citation: Dalton Trans., 2011,40, 7689-7692
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    Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

    T. Beweries, S. Hansen, M. Kessler, M. Klahn and U. Rosenthal, Dalton Trans., 2011, 40, 7689
    DOI: 10.1039/C1DT10366K

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