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Issue 16, 2011
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[Mn(CO)4{S2CNMe(CH2CO2H)}], a new water-soluble CO-releasing molecule

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Abstract

[Mn(CO)4{S2CNMe(CH2CO2H)}], 1, is shown to be a CO releasing molecule providing at least three moles CO per mole of compound. The mechanism of CO loss is dissociative and reversible and was investigated using Gaussian 09 calculations. The reversible binding of CO results in a relatively stable solution of the compound, while in the presence of a CO receptor or a ligand to prevent the rebinding of CO, the CO is lost rapidly. The X-ray structure was determined.

Graphical abstract: [Mn(CO)4{S2CNMe(CH2CO2H)}], a new water-soluble CO-releasing molecule

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Publication details

The article was received on 21 Jan 2011, accepted on 02 Feb 2011 and first published on 14 Mar 2011


Article type: Paper
DOI: 10.1039/C1DT10125K
Citation: Dalton Trans., 2011,40, 4230-4235
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    [Mn(CO)4{S2CNMe(CH2CO2H)}], a new water-soluble CO-releasing molecule

    S. H. Crook, B. E. Mann, A. J. H. M. Meijer, H. Adams, P. Sawle, D. Scapens and R. Motterlini, Dalton Trans., 2011, 40, 4230
    DOI: 10.1039/C1DT10125K

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