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Issue 10, 2011
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Unique spin transition and wide thermal hysteresis loop for a cobalt(II) compound with long alkyl chain

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Abstract

The cobalt(II) compounds with long alkyl chains, [Co(C12-terpy)2](BF4)2·EtOH·0.5H2O(1·EtOH·0.5H2O) and [Co(C12-terpy)2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a “re-entrant spin crossover”. The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

Graphical abstract: Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

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Publication details

The article was received on 18 Aug 2010, accepted on 22 Nov 2010 and first published on 09 Dec 2010


Article type: Communication
DOI: 10.1039/C0DT01052A
Citation: Dalton Trans., 2011,40, 2167-2169
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    Unique spin transition and wide thermal hysteresis loop for a cobalt(II) compound with long alkyl chain

    S. Hayami, K. Kato, Y. Komatsu, A. Fuyuhiro and M. Ohba, Dalton Trans., 2011, 40, 2167
    DOI: 10.1039/C0DT01052A

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