Issue 20, 2011

Synthesis, structure and reactions of an amidinate stabilised trigallane

Abstract

The neutral trigallane R3Ga3I2 was obtained in high yields by reaction of “GaI” with the moderately sterically demanding lithium N,N′-dicyclohexylneopentylamidinate. Its chemical reactions with N-lithio-2-propanimine, sodium superhydride and elemental iodine were investigated. RI-DFT calculations have been performed to confirm the bonding situation. All compounds are characterised by crystal structure analysis and NMR-spectroscopy.

Graphical abstract: Synthesis, structure and reactions of an amidinate stabilised trigallane

Supplementary files

Article information

Article type
Paper
Submitted
08 Feb 2011
Accepted
03 Mar 2011
First published
06 Apr 2011

Dalton Trans., 2011,40, 5591-5598

Synthesis, structure and reactions of an amidinate stabilised trigallane

G. Linti and T. Zessin, Dalton Trans., 2011, 40, 5591 DOI: 10.1039/C1DT10209E

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