Issue 10, 2011
From the journal:

Dalton Transactions

Microporous sensor: gas sorption, guest exchange and guest-dependant luminescence of metal–organic framework†

Sergey A. Sapchenko,a   Denis G. Samsonenko,*ab   Danil N. Dybtsev,ac   Maxim S. Melgunovd  and  Vladimir P. Fedinab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, Russian Federation
E-mail: denis@niic.nsc.ru
Fax: +7 (383) 330 9489
Tel: +7 (383) 330 9490

b Novosibirsk State University, 2 Pirogova street, Novosibirsk, Russian Federation

c Division of the Advanced Materials Science, POSTECH, San 31, Hyojadong, Pohang, Republic of Korea

d Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 Acad. Lavrentiev Ave., Novosibirsk, Russian Federation

Abstract

Zn(II)-containing metal–organic framework (MOF) [Zn4(dmf)(ur)2(ndc)4] (ndc2− = 2,6-naphtalenedicarboxylate, ur = urotropin, dmf = N,N′-dimethylformamide) was synthesized and characterized by X-ray crystallography and gas sorption analysis. Host MOF retains its crystallinity after guest removal and exchange. Single-crystal to single-crystal formation of different host–guest systems with benzene and ferrocene was investigated. Interesting guest-depended luminescence properties of the porous host framework were observed.

Graphical abstract: Microporous sensor: gas sorption, guest exchange and guest-dependant luminescence of metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C0DT00999G
Article type
Paper
Submitted
12 Aug 2010
Accepted
14 Oct 2010
First published
22 Nov 2010

Dalton Trans., 2011,40, 2196-2203

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Microporous sensor: gas sorption, guest exchange and guest-dependant luminescence of metal–organic framework

S. A. Sapchenko, D. G. Samsonenko, D. N. Dybtsev, M. S. Melgunov and V. P. Fedin, Dalton Trans., 2011, 40, 2196 DOI: 10.1039/C0DT00999G

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