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Issue 9, 2011
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Inorganic–organic hybrid compounds based on molybdenum oxide chains and tetrazolate-bridged polymeric silver cations

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Abstract

Three inorganic–organic compounds based on [MoxOy]n chains, [Ag4(3-pttz)2Mo3O10] (1) (3-pttz = 5-(3-pyridyl) tetrazolate), [Ag4(2-pttz)2Mo4O13] (2) (2-pttz = 5-(2-pyridyl) tetrazolate), and [Ag4(pzttz)2Mo4O13] (3) (pzttz = 5-(pyrazinyl) tetrazolate), have been self-assembled, accompanied by in situ formation processes of the 5-substituted tetrazolate ligands under hydrothermal condition. Compound 1 features a 3D framework composed of [Mo3O10]2 chains cross-linked by [Ag4(3-pttz)2]2+ belts. Compounds 2 and 3 reveal the 3D structures based on [Mo4O13]2 chains pillared by silver tetrazolate polymeric chains. The three title compounds represent the first three examples that the tetrazolate ligands are introduced into the backbones of the [MoxOy]n anion chains.

Graphical abstract: Inorganic–organic hybrid compounds based on molybdenum oxide chains and tetrazolate-bridged polymeric silver cations

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Publication details

The article was received on 03 Jul 2010, accepted on 24 Sep 2010 and first published on 30 Nov 2010


Article type: Paper
DOI: 10.1039/C0DT00781A
Citation: Dalton Trans., 2011,40, 1866-1872
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    Inorganic–organic hybrid compounds based on molybdenum oxide chains and tetrazolate-bridged polymeric silver cations

    M. Yang, L. Chen, S. Lin, X. Chen and H. Huang, Dalton Trans., 2011, 40, 1866
    DOI: 10.1039/C0DT00781A

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