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Issue 2, 2011
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A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF3)6O·CF3CO2H: synthesis under mild conditions and catalytic transesterification and oxazoline formation

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Abstract

Synthesis of a trifluoroacetate-bridged tetranuclear zinc cluster and its trifluoroacetic acid (TFA) adduct under mild conditions (∼110 °C) was achieved. The catalytic activity and functional group tolerance of the TFA adduct in transesterification and oxazoline formation were almost identical to those of the original zinc cluster.

Graphical abstract: A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF3)6O·CF3CO2H: synthesis under mild conditions and catalytic transesterification and oxazoline formation

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Publication details

The article was received on 15 Nov 2010, accepted on 09 Dec 2010 and first published on 14 Feb 2011


Article type: Communication
DOI: 10.1039/C0CY00048E
Citation: Catal. Sci. Technol., 2011,1, 230-233
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    A trifluoroacetic acid adduct of a trifluoroacetate-bridged μ4-oxo-tetranuclear zinc cluster, Zn4(OCOCF3)6O·CF3CO2H: synthesis under mild conditions and catalytic transesterification and oxazoline formation

    Y. Hayashi, T. Ohshima, Y. Fujii, Y. Matsushima and K. Mashima, Catal. Sci. Technol., 2011, 1, 230
    DOI: 10.1039/C0CY00048E

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