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Issue 10, 2011
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Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

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Abstract

Palladium-catalyzed carbonylative coupling reactions of aromatic halides and related compounds have undergone a rapid development during recent years. Nowadays, a plethora of palladium catalysts are available for the synthesis of ketones, alkynones, chalcones, etc., which are important intermediates in the manufacture of dyes, pharmaceuticals, agrochemicals, and other industrial products. In this critical review, we summarize the development of these carbonylative transformations with carbon nucleophiles (136 references).

Graphical abstract: Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

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Publication details

The article was received on 20 Apr 2011 and first published on 27 Jul 2011


Article type: Critical Review
DOI: 10.1039/C1CS15109F
Citation: Chem. Soc. Rev., 2011,40, 4986-5009
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    Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

    X. Wu, H. Neumann and M. Beller, Chem. Soc. Rev., 2011, 40, 4986
    DOI: 10.1039/C1CS15109F

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