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Department of Physics and Astronomy, University of Rochester, Rochester, USA
E-mail: amywakim@pas.rochester.edu
; Fax: +1 585-273-3237
; Tel: +1 585-275-4975
Phys. Chem. Chem. Phys., 2011,13, 18887-18892
DOI:
10.1039/C1CP20928K
Received
25 Mar 2011,
Accepted
07 Jul 2011
First published online
01 Aug 2011
A combination of pulsed depletion spectroscopy and photoassociation spectroscopy is utilized to assign photoassociation spectra of NaCs. These methods investigate the ab initio Ω = 2 potential energy curve and indicate a previously unknown avoided crossing between the (3)Ω = 1 and (4)Ω = 1 electronic states. We present rotational assignments of deeply bound singlet ground state molecules, an improved C6 coefficient for the (4)Ω = 1 and assignments for all twenty-three photoassociation resonances detuned from the Cs 62P3/2 asymptote.
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