Issue 10, 2011

A variable series resistance mechanism to explain the negative capacitance observed in impedance spectroscopy measurements of nanostructured solar cells

Abstract

A simple model for conductivity modulation in a recombination diode is discussed to explain the observation of negative capacitance at forward bias observed in many optoelectronic devices. We formulate the basic recombination-modulation model in terms of an equivalent circuit for small ac perturbation and discuss the application of the results in measurements of impedance spectroscopy of dye-sensitized solar cells, organic solar cells and related systems.

Graphical abstract: A variable series resistance mechanism to explain the negative capacitance observed in impedance spectroscopy measurements of nanostructured solar cells

Article information

Article type
Paper
Submitted
16 Nov 2010
Accepted
05 Jan 2011
First published
24 Jan 2011

Phys. Chem. Chem. Phys., 2011,13, 4679-4685

A variable series resistance mechanism to explain the negative capacitance observed in impedance spectroscopy measurements of nanostructured solar cells

J. Bisquert, Phys. Chem. Chem. Phys., 2011, 13, 4679 DOI: 10.1039/C0CP02555K

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