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Issue 9, 2011
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Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments

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Abstract

We propose the use of the pulse electron double resonance (ELDOR) method to determine the effective saturation factor of nitroxide radicals for dynamic nuclear polarization (DNP) experiments in liquids. The obtained values for the nitroxide radical TEMPONE-D,15N at different concentrations are rationalized in terms of spin relaxation and are shown to fulfil the Overhauser theory.

Graphical abstract: Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments

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Publication details

The article was received on 12 Oct 2010, accepted on 04 Jan 2011 and first published on 24 Jan 2011


Article type: Communication
DOI: 10.1039/C0CP02126A
Citation: Phys. Chem. Chem. Phys., 2011,13, 3630-3633
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    Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments

    M. Türke and M. Bennati, Phys. Chem. Chem. Phys., 2011, 13, 3630
    DOI: 10.1039/C0CP02126A

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