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Issue 18, 2011
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Self-assembly of melem on Ag(111)—emergence of porous structures based on amino-heptazine hydrogen bonds

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Abstract

Self-assembly of melem on Ag(111) as studied by Scanning-Tunneling-Microscopy (STM) in ultra-high vacuum revealed a great structural variety. In total, five porous and two densely packed monolayer polymorphs were observed. All structures are stabilized by intermolecular hydrogen bonds, where melem–melem arrangements are based on very few basic motifs. Six out of seven polymorphs can be described by a unified concept.

Graphical abstract: Self-assembly of melem on Ag(111)—emergence of porous structures based on amino-heptazine hydrogen bonds

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Publication details

The article was received on 21 Mar 2011, accepted on 09 May 2011 and first published on 22 Jun 2011


Article type: Paper
DOI: 10.1039/C1CE05342F
Citation: CrystEngComm, 2011,13, 5559-5565
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    Self-assembly of melem on Ag(111)—emergence of porous structures based on amino-heptazine hydrogen bonds

    J. Eichhorn, S. Schlögl, B. V. Lotsch, W. Schnick, W. M. Heckl and M. Lackinger, CrystEngComm, 2011, 13, 5559
    DOI: 10.1039/C1CE05342F

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