trans-N,N′-Dibenzyldiaminocyclohexane (B) crystallizes with 2,3-dichlorophenylacetic acid (AH); the crystal structure, resolved by using crystal X-ray diffraction, revealed an odd stoichiometry composed of H2B2+, two A− and two AH forming an unexpected hybrid salt–cocrystal. As this compound is a stable conglomerate (i.e. every single crystal contains the enantiomerically pure cation H2B2+, RR or SS), several preferential crystallization attempts (AS3PC) were performed in methanol and in THF and gave unexpected final enantiomeric excesses greater than 20% for the entrainment in methanol. These results suggest that the crystal growth mechanism preferentially involves building units composed of [H2B2+; 2A− and 2AH] or reconstruction of some crystal interfaces rather than a layer by layer construction.
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