Issue 15, 2011

Crystal engineering with dithiadiazolyl radicals

Abstract

The dithiadiazolyl radicals are a group of heterocyclic sulfur–nitrogen-containing neutral radicals. These molecules have received a great deal of attention due to their potential as building blocks for the development of molecular magnets and molecular conductors. Both magnetic and conducting properties are directly related to solid-state structure, and as a result dithiadiazolyl radicals have been the target of numerous systematic studies into the effects of molecular structure on crystal structure. This article will trace the advances in understanding of the factors affecting solid-state structure in this interesting class of molecules.

Graphical abstract: Crystal engineering with dithiadiazolyl radicals

Article information

Article type
Highlight
Submitted
18 Feb 2011
Accepted
11 Apr 2011
First published
16 May 2011

CrystEngComm, 2011,13, 4793-4805

Crystal engineering with dithiadiazolyl radicals

D. A. Haynes, CrystEngComm, 2011, 13, 4793 DOI: 10.1039/C1CE05217A

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