Issue 7, 2011
From the journal:

CrystEngComm

Metal–organic frameworks with rare topologies: lonsdaleite-type metal formates and their magnetic properties†

Hyunuk Kim,a   Yinyong Sun,a   Yonghwi Kim,a   Takashi Kajiwara,b   Masahiro Yamashita*b  and  Kimoon Kim*a  

* Corresponding authors

a National Creative Research Initiative Center for Smart Supramolecules (CSS), Department of Chemistry and Division of Advanced Materials Science (WCU project), Pohang University of Science and Technology (POSTECH), Pohang, Republic of Korea
E-mail: kkim@postech.ac.kr
Fax: +82-54-279-8129
Tel: +82-54-279-2113

b Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai, Japan
E-mail: yamasita@agnus.chem.tohoku.ac.jp

Abstract

Single-crystal X-ray analysis revealed that isomorphous metal formates [M6(HCOO)12]·DEF (M = Mg2+, Fe2+, Co2+, Zn2+) have a framework with the lonsdaleite net, which is one of the rare topologies in metal–organic frameworks; iron and cobalt formates with metal sites bridged by single atoms showed dominant ferromagnetic and antiferromagnetic interactions, respectively.

Graphical abstract: Metal–organic frameworks with rare topologies: lonsdaleite-type metal formates and their magnetic properties

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Article information

DOI
https://doi.org/10.1039/C1CE05031A
Article type
Communication
Submitted
09 Jan 2011
Accepted
26 Jan 2011
First published
14 Feb 2011

CrystEngComm, 2011,13, 2197-2200

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Metal–organic frameworks with rare topologies: lonsdaleite-type metal formates and their magnetic properties

H. Kim, Y. Sun, Y. Kim, T. Kajiwara, M. Yamashita and K. Kim, CrystEngComm, 2011, 13, 2197 DOI: 10.1039/C1CE05031A

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