Issue 8, 2011
From the journal:

CrystEngComm

Positional disorder of Cu(ii) ions in a cluster: a novel heptanuclear Cu(ii) core supported by 4-bromo-3,5-dimethylpyrazolate†

Yanqing Xu,a   Peilei Xia,a   Xiuteng Wang,cd   Wei Wei,*b   Fanzhou Zhanga  and  Changwen Hu*a  

* Corresponding authors

a Department of Chemistry, School of Science, Beijing Institute of Technology (BIT), Key Laboratory of Cluster Science (Beijing Institute of Technology), Ministry of Education in China, Beijing, PR China
E-mail: cwhu@bit.edu.cn
Fax: +86 10 68912631
Tel: +86 10 68912631

b Department of Chemistry, Capital Normal University, Beijing, PR China
E-mail: weiwei_cnu@163.com
Tel: +86 10 68902390

c College of Chemistry and Molecular Engineering, Peking University, Beijing, PR China

d Sub-institute of Resource and Environmental Standardization, China National Institute of Standardization, Beijing, PR China

Abstract

Two copper(II)-cluster complexes with intriguing heptanuclear cores have been synthesized and characterized by crystallographic and magnetic methods. Due to the positional disorder of copper(II) ions, the actual heptanuclear cluster demonstrates an asymmetric feature distinct from the previous reports.

Graphical abstract: Positional disorder of Cu(ii) ions in a cluster: a novel heptanuclear Cu(ii) core supported by 4-bromo-3,5-dimethylpyrazolate

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Article information

DOI
https://doi.org/10.1039/C0CE00933D
Article type
Communication
Submitted
09 Dec 2010
Accepted
14 Feb 2011
First published
08 Mar 2011

CrystEngComm, 2011,13, 2820-2823

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Positional disorder of Cu(II) ions in a cluster: a novel heptanuclear Cu(II) core supported by 4-bromo-3,5-dimethylpyrazolate

Y. Xu, P. Xia, X. Wang, W. Wei, F. Zhang and C. Hu, CrystEngComm, 2011, 13, 2820 DOI: 10.1039/C0CE00933D

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