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Issue 2, 2011
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Multidimensional frameworks constructed from Keggin-type heteropoly blue of molybdenum–tungsten cluster

Yuchao Wang,a  Lin Xu,*a  Ning Jiang,a  Lili Zhao,a  Fengyan Lia  and  Xizheng Liua 
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* Corresponding authors

a Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, PR China
E-mail: linxu@nenu.edu.cn
Fax: +86-431-85099668
Tel: +86-431-85099668

Abstract

The reaction of polyoxometalate anion [GeW11O39]8− with the complex anion [MoV2O4(H2O)2(ox)2]2− in the presence of CuCl2·2H2O and DMF (DMF = N,N-dimethyl formamide) at 85 °C in aqueous solution produces both a two-dimensional heteropoly blue H2[α-GeW10MoV2O40][Cu(DMF)3H2O]2·5H2O (1) and a three-dimensional heteropoly blue H4[α-GeW10MoV2O40]2 [CuK2(DMF)6] [K4(DMF)6] (2), which demonstrates that different molar ratio of W : Cu in the reaction could conduct different multidimensional structures of 2D and 3D. The magnetic investigation of the two compounds in temperature range from 300 K to 2 K indicated the presence of strong antiferromagnetic interactions related with the two MoV ions in these two compounds.

Graphical abstract: Multidimensional frameworks constructed from Keggin-type heteropoly blue of molybdenum–tungsten cluster

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Publication details

The article was received on 09 Aug 2010, accepted on 30 Oct 2010 and first published on 12 Nov 2010


Article type: Communication
DOI: 10.1039/C0CE00514B
Citation: CrystEngComm, 2011,13, 410-413
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    Multidimensional frameworks constructed from Keggin-type heteropoly blue of molybdenum–tungsten cluster

    Y. Wang, L. Xu, N. Jiang, L. Zhao, F. Li and X. Liu, CrystEngComm, 2011, 13, 410
    DOI: 10.1039/C0CE00514B

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