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Issue 5, 2011
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Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

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Abstract

A near identical MOF from the reaction between a homochiral ligand and LaIII ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.

Graphical abstract: Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

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Publication details

The article was received on 19 Jul 2010, accepted on 14 Oct 2010 and first published on 02 Nov 2010


Article type: Communication
DOI: 10.1039/C0CE00426J
Citation: CrystEngComm, 2011,13, 1277-1279
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    Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

    K. S. Jeong, B. H. Lee, Q. Li, S. B. Choi, J. Kim and N. Jeong, CrystEngComm, 2011, 13, 1277
    DOI: 10.1039/C0CE00426J

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