Bingel–Hirsch monoadducts of TiSc2N@Ih-C80versus Sc3N@Ih-C80: reactivity improvement via internal metal atom substitution

Shangfeng Yang; Chuanbao Chen; Xiaofang Li; Tao Wei; Fupin Liu; Song Wang

doi:10.1039/C3CC46277C

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Bingel–Hirsch monoadducts of TiSc₂N@I_h-C₈₀versus Sc₃N@I_h-C₈₀: reactivity improvement via internal metal atom substitution†

Shangfeng Yang,*^a Chuanbao Chen,^a Xiaofang Li,*^b Tao Wei,^a Fupin Liu^a and Song Wang^a

Author affiliations

* Corresponding authors

^a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion & Department of Materials Science and Engineering, University of Science and Technology of China (USTC), Hefei 230026, China
E-mail: sfyang@ustc.edu.cn
Fax: +86 551 6360 1750
Tel: +86 551 6360 1750

^b School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
E-mail: lixiaofang@iccas.ac.cn
Fax: +86 731 5829 0045
Tel: +86 731 5829 0052

Abstract

The first Bingel–Hirsch reaction of TiSc₂N@I_h-C₈₀ afforded two unconventional singly bonded monoadducts, revealing the dramatically improved reactivity compared to Sc₃N@I_h-C₈₀ and obvious change in the addition pattern.

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Article information

DOI: https://doi.org/10.1039/C3CC46277C
Article type: Communication
Submitted: 16 Aug 2013
Accepted: 29 Sep 2013
First published: 30 Sep 2013

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Chem. Commun., 2013,49, 10844-10846

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Bingel–Hirsch monoadducts of TiSc₂N@I_h-C₈₀versus Sc₃N@I_h-C₈₀: reactivity improvement via internal metal atom substitution

S. Yang, C. Chen, X. Li, T. Wei, F. Liu and S. Wang, Chem. Commun., 2013, 49, 10844 DOI: 10.1039/C3CC46277C

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