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Issue 44, 2011
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Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

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Abstract

An efficient strategy for the oxidative carbonylation of aromatic amidesvia C–H/N–H activation to form phthalimides using an Rh(III) catalyst has been developed. The reaction shows a preference for C–H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.

Graphical abstract: Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

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Publication details

The article was received on 21 Sep 2011, accepted on 04 Oct 2011 and first published on 17 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC15843K
Citation: Chem. Commun., 2011,47, 12074-12076
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    Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

    Y. Du, T. K. Hyster and T. Rovis, Chem. Commun., 2011, 47, 12074
    DOI: 10.1039/C1CC15843K

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