Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

Jerome Canivet; Sonia Aguado; Gerard Bergeret; David Farrusseng

doi:10.1039/C1CC15541E

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Chemical Communications

Issue 42, 2011

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Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

Jerome Canivet , Sonia Aguado , Gerard Bergeret and David Farrusseng

Chem. Commun., 2011, 47, 11650-11652

DOI: 10.1039/C1CC15541E
Received 07 Sep 2011, Accepted 21 Sep 2011
First published on the web 30 Sep 2011

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Covalent post-synthetic modification of a MOF, (In) MIL-68-NH₂, is carried out in a novel fashion to immobilize amino acids within the structure. Solid-phase peptide coupling methodology opens new perspectives for anchoring chiral bio- and catalytically active species. This could facilitate the immobilization of highly active and/or coordinating moieties inside MOF cavities.

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Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

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