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Issue 44, 2011
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Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(II) complex

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Abstract

Reaction of 3,5-(CF3)2PzLi with anhydrous RhCl3 in THF gives [Li(THF)]2Rh(μ-3,5-(CF3)2Pz)4 (1) as a rare example of a mononuclear, paramagnetic Rh(II) complex (Pz = pyrazolate).

Graphical abstract: Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(ii) complex

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Publication details

The article was received on 01 Sep 2011, accepted on 26 Sep 2011 and first published on 11 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC15428A
Citation: Chem. Commun., 2011,47, 12164-12166
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    Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(II) complex

    W. J. McCarty, X. Yang and R. A. Jones, Chem. Commun., 2011, 47, 12164
    DOI: 10.1039/C1CC15428A

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