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Issue 42, 2011
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Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

Fang Wang,a  Wen-Bin He,a  Jin-He Wang,a  Xiao-Sheng Yan,a  Ying Zhan,a  Ying-Ying Ma,b  Li-Cai Ye,a  Rui Yang,b  Fu Cai,a  Zhao Lia  and  Yun-Bao Jiang*a 
Author affiliations

* Corresponding authors

a Department of Chemistry, College of Chemistry and Chemical Engineering, and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China
E-mail: ybjiang@xmu.edu.cn
Fax: +86 592 218 5662
Tel: +86 592 218 8372

b College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

Abstract

N-Amidothioureas generated from amine-dimethylated natural L-phenylalanine and its D-enantiomer bearing a chiral carbon that is by 2 atoms or 3 chemical bonds away from the anion binding site establish chiral communication upon acetate anion binding to the thiourea moiety.

Graphical abstract: Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

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Publication details

The article was received on 11 Aug 2011, accepted on 07 Sep 2011 and first published on 30 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14995D
Citation: Chem. Commun., 2011,47, 11784-11786
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    Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

    F. Wang, W. He, J. Wang, X. Yan, Y. Zhan, Y. Ma, L. Ye, R. Yang, F. Cai, Z. Li and Y. Jiang, Chem. Commun., 2011, 47, 11784
    DOI: 10.1039/C1CC14995D

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