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Issue 43, 2011
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A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

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Abstract

PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature.

Graphical abstract: A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

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Publication details

The article was received on 29 Jul 2011, accepted on 27 Aug 2011 and first published on 07 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC14682C
Citation: Chem. Commun., 2011,47, 11855-11857
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    A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation

    A. J. Nuñez, L. N. Shear, N. Dahal, I. A. Ibarra, J. Yoon, Y. K. Hwang, J. Chang and S. M. Humphrey, Chem. Commun., 2011, 47, 11855
    DOI: 10.1039/C1CC14682C

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