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Issue 37, 2011
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Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

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Abstract

Asymmetric addition of arylboroxines to β-alkoxyacrylate esters proceeded in the presence of a rhodium complex coordinated with a chiral diene ligand to give high yields of β-alkoxy-β-arylcarboxylic acid esters with very high enantioselectivity.

Graphical abstract: Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

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Publication details

The article was received on 11 Jul 2011, accepted on 29 Jul 2011 and first published on 17 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC14150C
Citation: Chem. Commun., 2011,47, 10488-10490
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    Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

    T. Nishimura, A. Kasai, M. Nagaosa and T. Hayashi, Chem. Commun., 2011, 47, 10488
    DOI: 10.1039/C1CC14150C

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