A 1D MoVMnIII chain compound balanced by {Fe[HC(3,5-Me2pz)3]2}2+ dications was prepared. This complex displays a typical single-chain magnet character associated with the MoVMnIII chain and a spin crossover phenomenon arising from cationic Fe(II) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.
The article was received on 18 Jun 2011, accepted on 27 Jul 2011 and first published on 11 Aug 2011
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