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Issue 34, 2011
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Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate

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Abstract

Described is a concise synthesis of the 20,21-dihydro analog of N-methylwelwitindolinone B isothiocyanate, wherein a cationic homoallyl to cyclopropylmethyl rearrangement is circumvented by hydrogenation of the offending double bond.

Graphical abstract: Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate

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Publication details

The article was received on 14 Jun 2011, accepted on 14 Jul 2011 and first published on 27 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC13498A
Citation: Chem. Commun., 2011,47, 9705-9707
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    Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate

    V. Bhat and V. H. Rawal, Chem. Commun., 2011, 47, 9705
    DOI: 10.1039/C1CC13498A

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