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Issue 35, 2011
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Synthesis and optical resolution of a Cu(I) double-stranded helicate with ketimine-bridged tris(bipyridine) ligands

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Abstract

A tetranuclear Cu(I) double-stranded helicate was synthesized from ketimine-bridged tris(bipyridine) ligands and Cu(I) ions, and the racemate was successfully resolved by diastereomeric salt formation using an optically pure phosphate anion followed by anion exchange with NaPF6 without racemization.

Graphical abstract: Synthesis and optical resolution of a Cu(i) double-stranded helicate with ketimine-bridged tris(bipyridine) ligands

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Publication details

The article was received on 05 Jun 2011, accepted on 18 Jul 2011 and first published on 05 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13333K
Citation: Chem. Commun., 2011,47, 9795-9797
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    Synthesis and optical resolution of a Cu(I) double-stranded helicate with ketimine-bridged tris(bipyridine) ligands

    Y. Furusho, H. Goto, K. Itomi, H. Katagiri, T. Miyagawa and E. Yashima, Chem. Commun., 2011, 47, 9795
    DOI: 10.1039/C1CC13333K

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