Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 35, 2011
Previous Article Next Article

Redox control of a polymerization catalyst by changing the oxidation state of the metal center

Author affiliations

Abstract

The activity of cerium alkoxide complexes supported by a Schiff base ligand was controlled using redox reagents during the ring-opening polymerization of L-lactide. The rate of L-lactide polymerization was modified by switching in situ between the cerium(III) and cerium(IV) species.

Graphical abstract: Redox control of a polymerization catalyst by changing the oxidation state of the metal center

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 27 May 2011, accepted on 13 Jul 2011 and first published on 05 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13117F
Citation: Chem. Commun., 2011,47, 9897-9899
  •   Request permissions

    Redox control of a polymerization catalyst by changing the oxidation state of the metal center

    E. M. Broderick, N. Guo, T. Wu, C. S. Vogel, C. Xu, J. Sutter, J. T. Miller, K. Meyer, T. Cantat and P. L. Diaconescu, Chem. Commun., 2011, 47, 9897
    DOI: 10.1039/C1CC13117F

Search articles by author