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Issue 28, 2011
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Synthesis and chiroptical properties of ferrocene-[4]-helicenequinones: kinetic resolution of a planar-chiral diene

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Abstract

Both enantiomers of ferrocene [4]-helicenequinone 6, showing planar and helical chiralities, have been synthesized with very high optical purities using, as the key step, a kinetic resolution process between planar-chiral racemic ferrocene diene 2 and enantiopure sulfinyl benzoquinone (S)-3.

Graphical abstract: Synthesis and chiroptical properties of ferrocene-[4]-helicenequinones: kinetic resolution of a planar-chiral diene

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Publication details

The article was received on 18 May 2011, accepted on 02 Jun 2011 and first published on 20 Jun 2011


Article type: Communication
DOI: 10.1039/C1CC12921J
Citation: Chem. Commun., 2011,47, 8103-8105
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    Synthesis and chiroptical properties of ferrocene-[4]-helicenequinones: kinetic resolution of a planar-chiral diene

    A. Latorre, A. Urbano and M. Carmen Carreño, Chem. Commun., 2011, 47, 8103
    DOI: 10.1039/C1CC12921J

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