Issue 30, 2011
From the journal:

Chemical Communications

A 3D CoII framework with alternating vertex- and edge-sharing Δ-ribbons showing a two-step field-induced magnetic transition†

En-Cui Yang,*a   Zhong-Yi Liu,a   Xiao-Yun Wua  and  Xiao-Jun Zhao*a  

* Corresponding authors

a College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, P. R. China
E-mail: xiaojun_zhao15@yahoo.com.cn
Fax: +86-22-23766556
Tel: +86-22-23766556

Abstract

A novel 3D framework with vertex- and edge-sharing Δ-ribbons extended by ip2− connectors, {[Co7(H2O)2(μ3-OH)4(atz)2(ip)4]·5H2O}n (atz− = 5-amino-tetrazolate and ip2− = isophthalate), exhibits a two-step field-induced metamagnetic transition from an antiferromagnetic ordering to a weak spontaneous magnetization state by spin-competition at 2.0 KOe, followed by a spin-flop transition at 22.5 KOe.

Graphical abstract: A 3D CoII framework with alternating vertex- and edge-sharing Δ-ribbons showing a two-step field-induced magnetic transition

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC12796A
Article type
Communication
Submitted
12 May 2011
Accepted
18 Jun 2011
First published
30 Jun 2011

Chem. Commun., 2011,47, 8629-8631

Permissions

Request permissions

A 3D CoII framework with alternating vertex- and edge-sharing Δ-ribbons showing a two-step field-induced magnetic transition

E. Yang, Z. Liu, X. Wu and X. Zhao, Chem. Commun., 2011, 47, 8629 DOI: 10.1039/C1CC12796A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements