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Issue 29, 2011
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Catalytic decarboxylative alkylation of β-keto acids with sulfonamidesvia the cleavage of carbon–nitrogen and carbon–carbon bonds

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Abstract

An efficient decarboxylative alkylation reaction of β-keto acids with N-benzylic or N-allylic sulfonamides has been developed, for the first time, through sequential cleavage of carbon–nitrogen and carbon–carbon bonds in the presence of 10 mol% of FeCl3.

Graphical abstract: Catalytic decarboxylative alkylation of β-keto acids with sulfonamidesvia the cleavage of carbon–nitrogen and carbon–carbon bonds

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Publication details

The article was received on 12 May 2011, accepted on 07 Jun 2011 and first published on 22 Jun 2011


Article type: Communication
DOI: 10.1039/C1CC12790J
Citation: Chem. Commun., 2011,47, 8343-8345
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    Catalytic decarboxylative alkylation of β-keto acids with sulfonamidesvia the cleavage of carbon–nitrogen and carbon–carbon bonds

    C. Yang, J. Wang and S. Tian, Chem. Commun., 2011, 47, 8343
    DOI: 10.1039/C1CC12790J

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