Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32−: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}

M. Nieves Corella-Ochoa; Haralampos N. Miras; Alastair Kidd; De-Liang Long; Leroy Cronin

doi:10.1039/C1CC12782A

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Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO₃²⁻: {Mo₁₂V₁₂Te₃}, {Mo₁₂V₁₂Te₂} and {Mo₁₇V₈Te}†

M. Nieves Corella-Ochoa,^a Haralampos N. Miras,^a Alastair Kidd,^a De-Liang Long^a and Leroy Cronin*^a

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* Corresponding authors

^a WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland, UK
E-mail: L.Cronin@chem.gla.ac.uk
Web: http://www.chem.gla.ac.uk/staff/lee

Abstract

The influence of the pyramidal heteroanion, TeO₃²⁻ in the self-assembly of mixed metal (Mo/V) systems, is demonstrated by the isolation of three novel mixed-metal, mixed-valence architectures, {Mo₁₂V₁₂Te₃} (1), {Mo₁₂V₁₂Te₂} (2) and {Mo₁₇V₈Te} (3) with the tellurium centres exhibiting the novel μ₈-TeO₄ and μ₉-TeO₃ coordination modes while compounds 1 and 2 were discovered utilizing ESI mass spectrometry.

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Article information

DOI: https://doi.org/10.1039/C1CC12782A
Article type: Communication
Submitted: 12 May 2011
Accepted: 08 Jun 2011
First published: 06 Jul 2011

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Chem. Commun., 2011,47, 8799-8801

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Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO₃²⁻: {Mo₁₂V₁₂Te₃}, {Mo₁₂V₁₂Te₂} and {Mo₁₇V₈Te}

M. N. Corella-Ochoa, H. N. Miras, A. Kidd, D. Long and L. Cronin, Chem. Commun., 2011, 47, 8799 DOI: 10.1039/C1CC12782A

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