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Issue 35, 2011
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Encoded dendrimers with defined chiral composition via ‘click’ reaction of enantiopure building blocks

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Abstract

Dendrimers with end-groups of defined chiral composition have been prepared from alkyne functional enantio-pure building blocks obtained by selective enzymatic (ADH) ketone reductions using click chemistry. Optical rotation and enantioselective enzymatic modification is in agreement with the chiral composition of the dendrimers and permits unique molecular-level encoding of stereoisomeric dendritic libraries.

Graphical abstract: Encoded dendrimers with defined chiral composition via ‘click’ reaction of enantiopure building blocks

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Publication details

The article was received on 26 Apr 2011, accepted on 08 Jul 2011 and first published on 26 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12434J
Citation: Chem. Commun., 2011,47, 9870-9872
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    Encoded dendrimers with defined chiral composition via ‘click’ reaction of enantiopure building blocks

    B. Yeniad, H. Naik, R. J. Amir, C. E. Koning, C. J. Hawker and A. Heise, Chem. Commun., 2011, 47, 9870
    DOI: 10.1039/C1CC12434J

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