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Issue 27, 2011
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A regio- and stereoselective synthesis of trisubstituted alkenesviagold(I)-catalyzed hydrophosphoryloxylation of haloalkynes

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Abstract

A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubstituted alkenes.

Graphical abstract: A regio- and stereoselective synthesis of trisubstituted alkenesviagold(i)-catalyzed hydrophosphoryloxylation of haloalkynes

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Publication details

The article was received on 11 Apr 2011, accepted on 24 May 2011 and first published on 06 Jun 2011


Article type: Communication
DOI: 10.1039/C1CC12052B
Citation: Chem. Commun., 2011,47, 7851-7853
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    A regio- and stereoselective synthesis of trisubstituted alkenesviagold(I)-catalyzed hydrophosphoryloxylation of haloalkynes

    B. C. Chary, S. Kim, D. Shin and P. H. Lee, Chem. Commun., 2011, 47, 7851
    DOI: 10.1039/C1CC12052B

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