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Issue 23, 2011
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Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex

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Abstract

Highly regio- and stereoselective hydrothiolation of a wide range of alkynes with various thiols was demonstrated in the presence of a well-defined Rh complex supported on mesoporous SBA-15 silica. The catalyst was easily recovered and reused several times without significant loss of activity or selectivity.

Graphical abstract: Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex

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Publication details

The article was received on 20 Mar 2011, accepted on 28 Apr 2011 and first published on 16 May 2011


Article type: Communication
DOI: 10.1039/C1CC11605C
Citation: Chem. Commun., 2011,47, 6557-6559
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    Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex

    Y. Yang and R. M. Rioux, Chem. Commun., 2011, 47, 6557
    DOI: 10.1039/C1CC11605C

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