Issue 23, 2011
From the journal:

Chemical Communications

Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex†

Yong Yanga  and  Robert M. Rioux*a  

* Corresponding authors

a Department of Chemical Engineering, The Pennsylvania State University, 165 Fenske Laboratory, University Park, USA
E-mail: rioux@engr.psu.edu
Fax: +1-814-865-7846
Tel: +1-814-867-2503

Abstract

Highly regio- and stereoselective hydrothiolation of a wide range of alkynes with various thiols was demonstrated in the presence of a well-defined Rh complex supported on mesoporous SBA-15 silica. The catalyst was easily recovered and reused several times without significant loss of activity or selectivity.

Graphical abstract: Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex

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Article information

DOI
https://doi.org/10.1039/C1CC11605C
Article type
Communication
Submitted
20 Mar 2011
Accepted
28 Apr 2011
First published
16 May 2011

Chem. Commun., 2011,47, 6557-6559

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Highly regio- and stereoselective hydrothiolation of acetylenes with thiols catalyzed by a well-defined supported Rh complex

Y. Yang and R. M. Rioux, Chem. Commun., 2011, 47, 6557 DOI: 10.1039/C1CC11605C

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