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Issue 22, 2011
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Organic–inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O

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Abstract

The reaction of the basic bismuth nitrate [Bi6O4(OH)4](NO3)6·H2O with sodium methacrylate in DMSO gave [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O (OMc = O2CC3H5), which is highly soluble in organic solvents. By copolymerization of the bismuth oxido cluster with methyl methacrylate transparent, radiopaque organic–inorganic hybrid materials were obtained.

Graphical abstract: Organic–inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O

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Publication details

The article was received on 04 Mar 2011, accepted on 11 Apr 2011 and first published on 03 May 2011


Article type: Communication
DOI: 10.1039/C1CC11299F
Citation: Chem. Commun., 2011,47, 6353-6355
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    Organic–inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O

    L. Miersch, T. Rüffer and M. Mehring, Chem. Commun., 2011, 47, 6353
    DOI: 10.1039/C1CC11299F

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